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“Controlling pH in a Precipitation Plant”

Authors: Kjell Støle-Hansen and Bjarne A. Foss
Affiliation: NTNU, Department of Cybernetics
Reference: 1997, Vol. 18, No. 4, pp. 261-272.

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Keywords: pH control, metals, chemical industry, dynamic models

Abstract: This paper deals with pH control in a precipitation and dissolution process. The process is a part of the electrolyte purification plant at Falconbridge Nikkelverk in Kristiansand, Norway. The process including the present strategy for pH control are presented, and experienced weaknesses with this strategy are described. A rigorous dynamic model of the process is briefly summarized. This model was developed in earlier work with the purpose of being a tool for control design. Because of the precipitation in form of hydroxides and the limited dissolution rate of nickel carbonate, the process is approximately linear in pH. Therefore, an alternative strategy for pH control based on adding derivative and feed forward action is suggested. The alternative control strategy is by simulations shown to give severe improvements in performance. The robustness of the proposed controller is briefly analysed.

PDF PDF (1928 Kb)        DOI: 10.4173/mic.1997.4.2

DOI forward links to this article:
[1] Juri M. Seletzky Ute Noak Jens Fricke Eike Welk Werner Eberhard Christof Knocke Jochen Büchs, (2007), doi:10.1002/bit.21359


References:
[1] Asbjørnsen, O. A. (1972). Reaction invariants in the control of continuous chemical reactions. Chem. Eng. Sci., 27, pp.709-717, doi:10.1016/0009-2509(72)85007-3
[2] FNA, (1994-97). Private communication with personnel at Falconbridge Nikkelverk A/S during the period 1994 - 1997.
[3] Gustafsson, T. K., Skifvars, B. O., Sandström, K. V. and Waller, K. V. (1995). Modelling of pH for Control. Ind. Eng. Chem. Res., 34, 820-827, doi:10.1021/ie00042a014
[4] Gustafsson, T. K. and Waller, K. V. (1992). Nonlinear and Adaptive Control of pH. Ind. Eng. Chem. Res., 31, 2681-2693, doi:10.1021/ie00012a009
[5] Herskovitch, H. Z., McAvoy, T.J. and Athansios, I.L. (1978). Can. Journal of Chem. Eng., 56.
[6] Holcroft, G., Rosato, L., Perrier, M. and Berk, D. (1995). Dynamics of the Jarosite Conversion Process. Preprints from DYCORD+’95, Helsingør, Denmark.
[7] McAvoy, T. J., Hsu, E. and Lowenthal, S. (1972). Dynamics of pH in a Controlled Stirred Tank Reactor. Ind. Eng. Chem. Proc. Dev., 11, 68-70, doi:10.1021/i260041a013
[8] Newell, R. B. and Lee, P. L. (1988). Applied process control - a case study. Prentice Hall.
[9] Rosseland, E. W. (1993). Operational manual for the electrolyte purification section. Falconbridge Nikkelverk, Kristiansand (in Norwegian).
[10] Sandström, K. V. and Gustafsson, T. K. (1994). A study of the dynamics of calcium-phosphate precipitation in pH-control systems. Report 94-5, Åbo Akademi, Process Control Laboratory.
[11] Slotine, J.-J. E. and Li, W. (1991). Applied Nonlinear Control. Prentice-Hall International, Inc.
[12] Støle-Hansen, K. and Dotterud, O.M. (1996). Dynamic Modelling of a Precipitation Process in an Aqueous Solution. Computers chem. Engng., 20, Suppl., ppS629-634.
[13] Traa, S. (1994). Precipitation of Lead from Nickel Chloride Solutions. M.Sc. thesis (in Norwegian). Dep. of Chemical Engineering, the Norwegian Institute of Technology.
[14] Waller, K. V. and Gustafsson, T. K. (1986). Fundamental Properties of Continous pH Control. ISA Trans. 22, No. 1. 12-34.
[15] Waller, K. V. and Mäkilä, P. M. (1981). Chemical Reaction Invariants and Variants and Their Use in Reactor Modelling, Simulation and Control. Ind. Eng. Chem. Proc. Dev., 20, 1-11, doi:10.1021/i200012a001
[16] Wright, R. A. and Kravaris, C. (1995). pH Control in the Presence of Precipitation Equilibria. Preprints from DYCORD+’95, Helsingør, Denmark


BibTeX:
@article{MIC-1997-4-2,
  title={{Controlling pH in a Precipitation Plant}},
  author={St{\o}le-Hansen, Kjell and Foss, Bjarne A.},
  journal={Modeling, Identification and Control},
  volume={18},
  number={4},
  pages={261--272},
  year={1997},
  doi={10.4173/mic.1997.4.2},
  publisher={Norwegian Society of Automatic Control}
};

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